Volume 285
Main Index

Issues 1-3, Pages C1-C36, 1-460 (16 April 1985)

Editorial note Page ix C. Eaborn, R.B. King, E.O. Fischer, M. Kumada, J.F. Normant, O.A. Reutov

On the steric course of addition of 1-lithio- and 1-magnesio-2-pivaloyl-1,2,3,4-tetrahydroisoquinoline to aldehydes and ketones. An x-ray crystal structure determination of the organomagnesium reagent Pages 1-13 Dieter Seebach, Jesper Hansen, Paul Seiler, Jack M. Gromek

Pentadienylmetal compounds. Structural analyses and applications in organic synthesis Pages 15-29 Hajime Yasuda, Akira Nakamura

Allylic organometallic way to control acyclic stereochemistry and its application to the synthesis of carbohydrates Pages 31-42 Yoshinori Yamamoto, Toshiaki Komatsu, Kazuhiro Maruyama

Some novelties in olefin carbometallation assisted by alkyl-magnesium and -aluminium derivatives and catalyzed by zirconium and titanium complexes Pages 43-51 U.M. Dzhemilev, O.S. Vostrikova

The preparation of Grignard reagents via the hydromagnesation reaction and their uses in organic synthesis Pages 53-64 Fumie Sato

Lithium tris(phenylthio)methane for the homologation of trialkylboranes: Convenient syntheses of ketones and t-carbinols Pages 65-69 Andrew Pelter, J.Madhusudhana Rao

A new method for the synthesis of vinyl- and di-allenes assisted by organoaluminium compounds Pages 71-82 G.A. Tolstikov, T.Yu. Romanova, A.V. Kuchin

Nucleophilic cleavage of acetals using organometallic reagents Pages 83-94 Atsunori Mori, Junya Fujiwara, Keiji Maruoka, Hisashi Yamamoto

Chemistry of organosilicon compounds: CC. Allyl coupling reactions of allylsilanes and allylstannanes with allylic halides, ethers and acetates promoted by a Lewis acid Pages 95-107 Akira Hosomi, Takafumi Imai, Masahiko Endo, Hideki Sakurai

Silicon in organic synthesis. Stereoselective synthesis of some insect sex pheromones Pages 109-119 T.H. Chan, K. Koumaglo

Sulfone reagents in organic synthesis: VI. Sulfonyl- and silyl-substituted hydrocarbons as versatile carbanion precursors in organic synthesis Pages 121-136 John J. Eisch, Mohammad Behrooz, Suresh K. Dua

Synthetic organic reactions by means of reactive nucleophiles generated through rearrangement of a silyl group Pages 137-148 Isao Kuwajima

α-Ethoxybutenyltributyletains precurseurs d'α-ethoxybutenyllithiums: Application a la synthese d'enones via les monoethers homoallyliques d'α-glycols Pages 149-162 Jean-Paul Quintard, Bernard Elissondo, Thomas Hattich, Michel Pereyre

Regio- and stereo-selective synthesis of vinylstannanes. Transition-metal catalyzed stannylmetalation of acetylenes and conversion of enol triflates and vinyl iodides into vinylstannanes Pages 163-172 Seijiro Matsubara, Jun-Ichi Hibino, Yoshitomi Morizawa, Koichiro Oshima, Hitosi Nozaki

Stereospecific cyclopropane synthesis from γ-stannyl alcohols Pages 173-191 Ian Fleming, Christopher J. Urch

Homogeneous hydrogenation of ketones using chromium hexacarbonyl as catalyst precursor in the presence of bases Pages 193-203 László Markó, Zsuzsa Nagy-Magos

Vinylketene: V. Abfangreaktionen von vinylketen-zwischenstufen-hydrochinon- versus lactonbildung Pages 205-211 Karl Heinz Dötz, Werner Sturm

Chiral acetate enolate equivalent for the synthesis of β-hydroxy acids and esters: X-ray crystal structure of RR,SS-(η5-C5H5)Fe(CO)(PPh3)(COCH2CH(OH)CH2CH3)] Pages 213-223 Stephen G. Davies, Isabelle M. Dordor-Hedgecock, Peter Warner, Richard H. Jones, Keith Prout

Desulfurization of benzylic mercaptans by triiron dodecacarbonyl under acidic and biphasic conditions Pages 225-229 Howard Alper, Fazle Sibtain

Direct conversion of alkenes into methyl-substituted cyclopropanes using an organoiron ethylidene transfer reagent Pages 231-252 Kenneth A.M. Kremer, Paul Helquist

Organoiron complexes in organic synthesis: XXXII Synthesis of sterically crowded spirocyclic compounds using organoiron chemistry: An approach to acorane and cedrol synthesis Pages 253-265 Anthony J. Pearson, Trevor R. Perrior

Tricarbonyliron methoxycyclohexadiene and dienyl complexes: Preparation, properties and applications Pages 267-280 Arthur J. Birch, Lawrence F. Kelly

Asymmetric synthesis by chiral ruthenium complexes: XI. Asymmetric hydrogenation of tiglic acid in the presence of phosphine substituted ruthenium carbonyl carboxylates Pages 281-292 Ugo Matteoli, Gloria Menchi, Piero Frediani, Mario Bianchi, Franco Piacenti

Cobalt-catalysed carbonylation of aryl halides Pages 293-303 M. Foà, F. Francalanci, E. Bencini, A. Gardano

The chemistry of η5-CpCo(CO)(maleoyl) and η5-CpCo(CO)(phthaloyl) complexes Pages 305-319 Lanny S. Liebeskind, Charles F. Jewell Jr.

Catalytic decarbonylation, hydroacylation, and resolution of racemic pent-4-enals using chiral bis(di-tertiary-phosphine) complexes of rhodium(I) Pages 321-332 Brian R. James, Charles G. Young

Stereochemical control by carboxylate groups in homogeneous hydrogenation Pages 333-341 John M. Brown, Stephen A. Hall

Nickel-catalyzed oligomerization of functionalized conjugated dienes Pages 343-357 A. Tenaglia, P. Brun, B. Waegell

Regio- and stereo-chemistry in allylation of aryl Grignard reagents catalyzed by phosphine-nickel and -palladium complexes Pages 359-373 Tamio Hayashi, Mitsuo Konishi, Kan-Ichi Yokota, Makoto Kumada

The stereochemistry of organometallic compounds: XXXVI. Regio- and stereo-chemical control in the nickel-catalysed hydrocyanation of silylalkynes Pages 375-381 Neil J. Fitzmaurice, W.Roy Jackson, Patrick Perlmutter

A palladium-catalyzed cyclocarbonylation reaction leading to synthons for cyclopentanoid chemistry Pages 383-388 Emanuele Amari, Marta Catellani, Gian Paolo Chiusoli

Asymmetric induction during carbonylation of an optically active organopalladium. A novel and versatile route to enantiomeric glycerides. Pages 389-393 L.L. Troitskaya, V.I. Sokolov

Etude de la regioselectivite de la substitution des carbanions par des derives allyliques catalysee au palladium. Obtention selective de composes a carbone quaternaire Pages 395-413 Thérèse Cuvigny, Marc Julia, C. Rolando

Palladium-catalyzed synthesis of aromatic acid derivatives by carbonylation of aryl iodides and Alk3SnNu (Nu = MeO, Et2N, PhS, EtS) Pages 415-418 N.A. Bumagin, Yu.V. Gulevich, I.P. Beletskaya

The synthesis of a precursor to pentalenene using a palladium(O) catalysed (3 + 2) cycloaddition Pages 419-427 Raymond Baker, Rona B. Keen

Transformations of cyclopropane in rigid hydrocarbon systems using platinum(II) Pages 429-436 P.W. Jennings, R.E. Ekeland, M.D. Waddington, T.W. Hanks

More highly mixed, higher order cyanocuprates “RT(2-thienyl)Cu(CN)Li2”. Efficient reagents which promote selective ligand transfer Pages 437-447 Bruce H. Lipshutz, Joseph A. Kozlowski, David A. Parker, Sam L. Nguyen, Keith E. McCarthy

Selective catalyzed-rearrangement of terminal epoxides to methyl ketones Pages 449-460 J. Prandi, J.L. Namy, G. Menoret, H.B. Kagan

Metal-promoted cyclization: VI. Palladium-catalyzed cyclization via intramolecular allylation of alkenylmetals Pages C1-C4 Sugata Chatterjee, Ei-Ichi Negishi

Activation of alkylidene-bridged heterobimetallic complexes toward electrophilic attack Pages C5-C8 Susan M. Clift, Jeffrey Schwartz

Thallium in organic synthesis: XLIV. Electrophilic thallation of electron-rich arenes Pages C9-C12 Edward C. Taylor, Alan H. Katz, Sergio I. Alvarado, Alexander McKillop

Iron-catalyzed allylic alkylation Pages C13-C16 Sandra J. Ladoulis, Kenneth M. Nicholas

Natural product synthesis using π-allyltricarbonyliron lactone complexes: Synthesis of parasorbic acid, the carpenter bee pheromone and malyngolide Pages C17-C20 Averil M. Horton, Steven V. Ley

Selective 1,2-addition of organocerium(III) reagents to α,β-unsaturated carbonyl compounds Pages C21-C23 Tsuneo Imamoto, Yasushi Sugiura

A new method for stereocontrol in palladium-catalyzed reactions of allylic substrates Pages C24-C26 Ruth E. Nordberg, Jan-e. Bäckvall

An organometallic route to (±)3-p-toluenesulfinyl- 2-pyrone Pages C27-C30 Gary H. Posner, Wayne Harrison

Author index Page C31

Subject index Pages C32-C36